Topic 3

Elements, Compounds & Mixtures

All matter can be classified as either a pure substance (element or compound) or a mixture. Understanding the differences is fundamental to all of chemistry.

A. Classification of Matter

Element vs Compound vs Mixture

CategoryDefinitionKey PropertiesExamples
ElementPure substance made of only ONE type of atom. Cannot be broken down by chemical means.Fixed composition; unique set of physical and chemical propertiesO₂, Fe, Au, Na, H₂, N₂, C
CompoundTwo or more elements chemically combined in a FIXED ratio. Has properties completely different from its constituent elements.Fixed composition; can only be separated by CHEMICAL means (not physical); properties differ from elementsH₂O, NaCl, CO₂, H₂SO₄, CH₄, NH₃
MixtureTwo or more substances PHYSICALLY combined. Each substance retains its own properties.Variable composition; components retain individual properties; separated by PHYSICAL meansAir, seawater, soil, alloys, milk, crude oil
Element
DefinitionPure substance made of only ONE type of atom. Cannot be broken down by chemical means.
Key PropertiesFixed composition; unique set of physical and chemical properties
ExamplesO₂, Fe, Au, Na, H₂, N₂, C
Compound
DefinitionTwo or more elements chemically combined in a FIXED ratio. Has properties completely different from its constituent elements.
Key PropertiesFixed composition; can only be separated by CHEMICAL means (not physical); properties differ from elements
ExamplesH₂O, NaCl, CO₂, H₂SO₄, CH₄, NH₃
Mixture
DefinitionTwo or more substances PHYSICALLY combined. Each substance retains its own properties.
Key PropertiesVariable composition; components retain individual properties; separated by PHYSICAL means
ExamplesAir, seawater, soil, alloys, milk, crude oil
⚡ MCQ Tip Element = one atom type. Compound = chemically combined, fixed ratio, properties differ from elements. Mixture = physically combined, variable ratio. A compound's properties are DIFFERENT from its constituent elements — e.g. H₂ (flammable gas) + O₂ (supports combustion) → H₂O (liquid, extinguishes fire).

B. Types of Mixtures

Solution vs Colloid vs Suspension

TypeParticle SizeAppearanceSettles?Tyndall EffectExamples
Solution (Homogeneous)< 1 nmTransparent, clearNeverAbsentSaltwater, sugar in water, vinegar, air
Colloid1 – 1000 nmOften cloudy/translucentNever (stable)Present ✅Milk, fog, gelatin, blood, smoke, mayonnaise
Suspension (Heterogeneous)> 1000 nmCloudy/opaque, visible particlesYes, on standingPresentMuddy water, chalk in water, oil in water
Solution (Homogeneous)
Particle Size< 1 nm
AppearanceTransparent, clear
Settles?Never
Tyndall EffectAbsent
ExamplesSaltwater, sugar in water, vinegar, air
Colloid
Particle Size1 – 1000 nm
AppearanceOften cloudy/translucent
Settles?Never (stable)
Tyndall EffectPresent ✅
ExamplesMilk, fog, gelatin, blood, smoke, mayonnaise
Suspension (Heterogeneous)
Particle Size> 1000 nm
AppearanceCloudy/opaque, visible particles
Settles?Yes, on standing
Tyndall EffectPresent
ExamplesMuddy water, chalk in water, oil in water
Tyndall Effect Colloid particles scatter a beam of light — visible as a bright path (Tyndall beam) True solutions do NOT show Tyndall effect. Used to distinguish solutions from colloids.
⚡ MCQ Tip Tyndall effect is shown by COLLOIDS (and suspensions), NOT by true solutions. Milk = colloid. Saltwater = solution. Muddy water = suspension (settles).

C. Separation Techniques

Technique → What It Separates → Example

TechniquePrinciple / Used ForExample
FiltrationSeparates insoluble solid from a liquid using filter paperSand from water; chalk from water
EvaporationRemoves solvent by heating to recover dissolved solidSalt from saltwater (halite recovery)
DistillationSeparates liquids with significantly different boiling points — liquid vaporises, condenses, collected separatelyAlcohol from water; pure water from seawater
Fractional DistillationSeparates a mixture of liquids with close boiling points using a fractionating columnCrude oil into fractions; separation of liquid air
ChromatographySeparates mixtures based on different solubilities in a solvent and different attractions to the stationary phaseSeparating ink dyes; food colorings; amino acids
CrystallisationDissolves a substance in hot solvent, then cools slowly — pure crystals form and separatePurifying sugar; growing salt crystals
CentrifugationRapid spinning — denser particles settle to bottom (pellet); used for colloids and suspensionsSeparating blood components; cream from milk
DecantationCarefully pouring off the upper liquid after a suspension has settledMuddy water — pour off clear water
⚡ MCQ Tip Distillation separates by boiling point. Filtration separates insoluble solids. Chromatography separates by solubility. Fractional distillation = crude oil fractions. Centrifugation = blood components, milk.

Quick MCQ Revision

FactAnswer
Element definitionPure substance with only one type of atom — cannot be chemically broken down
Compound vs mixtureCompound: fixed ratio, chemical combination. Mixture: variable ratio, physical combination.
Tyndall effect seen inColloids (and suspensions) — NOT in true solutions
Milk is aColloid
Muddy water is aSuspension — settles on standing
Saltwater is aHomogeneous solution
Separating crude oil fractionsFractional distillation (by boiling point)
Separating sand from waterFiltration
Separating blood componentsCentrifugation
Separating ink dyesChromatography (by solubility)
Key