Topic 4

The Periodic Table

118 elements arranged in order of increasing atomic number. Developed by Dmitri Mendeleev (1869) based on atomic mass; revised using atomic number by Moseley.

A. Structure of the Periodic Table

Key Facts About the Table

  • 118 elements currently known
  • 7 Periods (horizontal rows) — the period number = number of electron shells the element has
  • 18 Groups (vertical columns) — elements in the same group have the same number of valence electrons and similar chemical properties
  • Groups 1–2 and 13–18: main group (s and p block) elements
  • Groups 3–12: transition metals (d block)
  • Metals are on the LEFT, non-metals on the RIGHT, metalloids along the staircase boundary
  • Mendeleev arranged by atomic mass and left gaps for undiscovered elements — his predictions were later confirmed
⚡ MCQ Tip Mendeleev = atomic mass (1869). Modern table = atomic number. Period = number of shells. Group = number of valence electrons (for main group elements).

B. Key Groups & Their Properties

Group 1 — 1 valence e⁻
Alkali Metals
Soft, highly reactive metals. React vigorously with water → metal hydroxide + H₂ gas. Form +1 ions. Reactivity increases down the group.
Li, Na, K, Rb, Cs, Fr
Group 2 — 2 valence e⁻
Alkaline Earth Metals
Reactive metals, harder than Group 1. Form +2 ions. React with water (less vigorously than Group 1).
Be, Mg, Ca, Sr, Ba, Ra
Groups 3–12
Transition Metals
Good conductors, high melting points, form coloured compounds and complex ions, variable valency (oxidation states).
Fe, Cu, Zn, Cr, Ni, Mn, Ti
Group 17 — 7 valence e⁻
Halogens
Very reactive non-metals. Exist as diatomic molecules (F₂, Cl₂…). Form −1 ions (halides). Reactivity DECREASES down group. Good oxidising agents.
F, Cl, Br, I, At
Group 18 — full outer shell
Noble Gases
Completely unreactive (inert) — full outer shell of 8 electrons (He = 2). Monoatomic. Used in lighting, balloons, and welding.
He, Ne, Ar, Kr, Xe, Rn

Quick MCQ Revision

FactAnswer
Mendeleev arranged byAtomic mass (1869) — gaps left for undiscovered elements
Modern table arranged byAtomic number (protons)
Period = Number of electron shells
Group = Number of valence electrons (main group)
Group 1 propertiesAlkali metals — soft, very reactive, form +1 ions, react with water
Group 17 propertiesHalogens — very reactive non-metals, form −1 ions, diatomic molecules
Group 18 propertiesNoble gases — inert, full outer shell, used in lighting
Atomic radius across periodDecreases → (more protons, same shells)
Electronegativity down groupDecreases ↓
Most electronegative elementFluorine (F) — top right of table
Key